195247-75-7Relevant academic research and scientific papers
A new synthesis of carbapentofuranoses from carbohydrates
Desire, Jerome,Prandi, Jacques
, p. 6189 - 6192 (1997)
Carbafuranosides were synthesized in one step from various O-protected 1,2,6-trideoxy-6-iodo-hex-1-enitols by cobalt catalyzed 5-exo radical-cyclization under molecular oxygen. Yields were fair to good with interesting selectivities.
The cobalt-catalyzed oxygenative radical route from hexopyranosides to carbapentofuranoses
Desire, Jerome,Prandi, Jacques
, p. 3075 - 3084 (2007/10/03)
Cobalt-catalyzed radical cyclization/oxygenation of various 6-iodohex-1-enitols gave in one step the carbocyclic analogs of pentofuranoses. The reaction was run under very mild conditions and gave moderate to good yields of carbapentofuranoses within a few hours. All the possible 6-iodohex-1-enitol stereoisomers were prepared, and the influence of relative configurations and protecting groups was studied.
