195372-29-3Relevant academic research and scientific papers
N-(2-bromophenyl)-2-(4,6-dimethoxypyrimidin-2-yloxy)benzylamine, a new selective postemergent herbicide for weed control in winter oilseed rape
Wu, Jun,Cheng, Jie,Lu, Long
, p. 5954 - 5957 (2006)
N-(2-Bromophenyl)-2-(4,6-dimethoxypyrimidin-2-yloxy)benzylamine is a highly active herbicide, which belongs to a novel class of chemistry. The compound is de novo synthesized in good yield, and the structure is confirmed by 1H NMR, IR, MS, micr
Palladium-Catalyzed Regioselective C-Benzylation via a Rearrangement Reaction: Access to Benzyl-Substituted Anilines
Amézquita-Valencia, Manuel,Alper, Howard
supporting information, p. 16774 - 16778 (2016/11/17)
An unprecedented C-benzylation rearrangement reaction, catalyzed by palladium, is reported. The reaction proceeds by rearrangement leading to the direct synthesis of para or ortho benzyl-substituted N-methylanilines. The product is obtained in high regioselectivity, without the need to use a ligand for the catalytic process.
Concise copper-catalyzed synthesis of tricyclic biaryl ether-linked aza-heterocyclic ring systems
Mestichelli, Paola,Scott, Matthew J.,Galloway, Warren R. J. D.,Selwyn, Jamie,Parker, Jeremy S.,Spring, David R.
supporting information, p. 5448 - 5451 (2013/11/19)
A new method for the synthesis of tricyclic biaryl ether-linked ring systems incorporating seven-, eight-, and nine-membered ring amines is presented. In the presence of catalytic quantities of copper(I), readily accessible acyclic precursors undergo an intramolecular carbon-oxygen bond-forming reaction facilitated by a templating chelating nitrogen atom. The methodology displays a broad substrate scope, is practical, and generates rare and biologically interesting tricyclic heteroaromatic products that are difficult to access by other means.
Synthesis of deuterated herbicidal ZJ0273, ZJ0702, ZJ0777, and SIOC0163
Yang, Zheng-Min,Lu, Long
experimental part, p. 192 - 197 (2011/07/09)
ZJ0273 (propyl 4-(2-(4,6-dimethoxypyrimidin-2-yloxy)benzylamino)benzoate), ZJ0702 (isopropyl 4-(2-(4,6-dimethoxy pyrimidin-2-yloxy)benzylamino)benzoate), ZJ0777 (2-bromo-N-(2-(4,6-dimethoxypyrimidin-2-yloxy)benzyl)aniline), and SIOC0163 (5-bromo-N-(2-(4,6
