Cas 195378-22-4,[Rh((CH3CO)2CH)(η(2)-CH(PiPr3)=C=CPh2)(PiPr3)]BF4

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Check Digit Verification of cas no

The CAS Registry Mumber 195378-22-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,9,5,3,7 and 8 respectively; the second part has 2 digits, 2 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 195378-22:
(8*1)+(7*9)+(6*5)+(5*3)+(4*7)+(3*8)+(2*2)+(1*2)=174
174 % 10 = 4
So 195378-22-4 is a valid CAS Registry Number.

195378-22-4Upstream product

195378-19-9 Rh((CH₃CO)2CH)(P(CH(CH₃)2)3)2(CHCC(C₆H₅)2)⁽¹⁺⁾*BF₄^(1-)=[Rh((CH₃CO)2CH)(P(CH(CH₃)2)3)2(CHCC(C₆H₅)2)]BF₄

195378-22-4Downstream Products

195378-22-4Relevant academic research and scientific papers

Reductive elimination of [Ph2C=C=CHPR3]BF4 from the rhodium(III)-allenyl derivatives [Rh(acac){CH=C=CPh2}(PR3)2]BF4 (PR3 = PCy3, PiPr3)

Esteruelas, Miguel A.,Lahoz, Fernando J.,Martín, Marta,O?ate, Enrique,Oro, Luis A.

, p. 4572 - 4580 (2008/10/08)

The olefinic unit of the complexes Rh(acac)(cyclooctadiene)(PR3) (PR3 = PCy3 (1), PiPr3 (2)) is displaced by 1,1-diphenyl-2-propyn-1-ol, to afford Rh(acac){η2-HC=CC(OH)Ph2}(PR3)

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