19543-98-7

Downstream Products

• 110118-62-2 {(η5-C5H5)(hydrido)(P(C6H5)3)2}Fe 
• 122382-02-9 dichloro(N-ethoxycarbonylpyrrole-2-thiocarboxamide)bis(triphenylphosphine)iron(II) 
• 90668-47-6 dichloro(triphenylphosphine)(N-sulphinylaniline)iron(II) 
• 207728-75-4 2,2-bis(diphenylphosphinomethyl)-3-η(5)-cyclopentadienyl-1-propanol-iron(II) chloride 
• 207728-76-5 acetic acid-2,2-bis(diphenylphosphinomethyl)-3-η(5)-cyclopentadienyl-1-propyl ester-iron(II) chloride 
• 110221-09-5 (η5-cyclopentadienyl)(η3-1-methylallyl)(triphenylphosphine)iron 
• 110118-42-8 (η5-cyclopentadienyl)ethylbis(triphenylphosphine)iron 
• 110118-60-0 (η5-cyclopentadienyl)(η2-ethylene)hydrido(triphenylphosphine)iron 

Relevant academic research and scientific papers

The Electro-Syntheses of Anhydrous Metal Chloride Complexes of Iron, Cobalt, and Nickel

The electro-syntheses of the anhydrous metal(II) chlorides od Fe, Co, and Ni are described.The appropriate metal is present in the form of a sacrificial anode and the reaction is carried out in an undivided cell with ethanolic solutions of hydrogen chloride.The primary products, MCl2 . n EtOH (1 - 3), are obtained in yields of 83 - 100percent based upon the current consumed and are converted into 4 - 6 upon reaction with THF, into 7 - 12 upon reaction with triorganophosphanes and into the tetrachlorometallate(II) complexes 13 - 15 upon reaction with Cl.Electrochemical reduction of nickel(II) chloride and triphenylphosphane (1 : 3) in THF leads to the formation of chlorotris(triphenylphosphane)nickel(I) (18) in 65percent yield.