195507-97-2Relevant academic research and scientific papers
Zur Synthese des 1,2-Diphenyldecamethylcyclohexasilans
Uhlig, Wolfram
, p. C6 - C8 (1993)
The title compound has been prepared by cyclization of 1,6-dibromo-3,4-diphenyldecamethylhexasilane with lithium. The cleavage of the silicon-phenyl bonds of the cyclohexasilane by CF3SO3H gives the 1,2-bis-triflate derivate.
Synthesis of siloxene-like polymers
Kleewein, Alois,Stueger, Harald
, p. 69 - 77 (2007/10/03)
Polysiloxane structures closely related to Kautsky's siloxene have been prepared starting from well defined cyclosilane units. The products exhibit moderate to strong fluorescence ranging from 400 to 550nm, depending on the ring size and the number and nature of substituents. No fluorescence was observed for products derived from linear silane units. The fluorescence is influenced by the functionality of the siloxane networks as shown in a comparison of cyclosilane compounds with one functionality per ring up to species with two functionalities per each silicon atom of the ring.
