195510-88-4

Upstream product

• 195324-77-7 6-[(R)-2-(2-Benzyloxy-1-methyl-ethyl)-hex-5-enyl]-2,3-dihydro-pyran-4-one 
• 195324-76-6 (Z)-(R)-7-(2-Benzyloxy-1-methyl-ethyl)-1-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-undeca-3,10-dien-5-one 
• 195324-74-4 (R)-7-Benzyloxy-5-(2,2-dimethoxy-ethyl)-6-methyl-heptan-2-ol 
• 195324-75-5 (R)-3-(2-Benzyloxy-1-methyl-ethyl)-hept-6-enal 
• 195324-73-3 (R)-3-(2,2-Dimethoxy-ethyl)-2-methyl-heptane-1,6-diol 
• 73770-45-3 (R)-(+)-7,7-dimethoxy-5-(1-methylethenyl)-2-heptanone 

Downstream Products

• 195324-78-8 (R)-7-(2-Benzyloxy-1-methyl-ethyl)-1-methyl-5,6,7,8-tetrahydro-naphthalen-2-ol 

Relevant academic research and scientific papers

Total synthesis of (±)-ligudentatol via photoaddition-fragmentation-aromatic annulation sequence

First synthesis of the naturally occurring compound (+)-ligudentatol is presented. It demonstrates the synthetic utility of the 'Photoaddition-Fragmentation-Aromatic Annulation' sequence, recently developed via the intramolecular photocycloaddition of dihydropyrones to alkenes.