195515-50-5Relevant academic research and scientific papers
Enantioselective catalytic Diels-Alder reaction of ethyl 2-benzoylacrylate with chiral bis(oxazoline)- or mono(oxazoline)-magnesium complex
Honda, Yuko,Date, Tadamasa,Hiramatsu, Hajime,Yamauchi, Masashige
, p. 1411 - 1412 (1997)
The magnesium catalysed Diels-Alder reaction of 2-benzoylacrylate gave the endo-adduct enantioselectively with bis(oxazoline) 5 as a C2-symmetric ligand or mono-(oxazoline) 4 as a non-C2-symmetric ligand.
Reactivity of 2-methylene-1,3-dicarbonyl compounds: Catalytic enantioselective Diels-Alder reaction
Yamauchi, Masashige,Aoki, Takashi,Li, Ming-Zhu,Honda, Yuko
, p. 3113 - 3118 (2007/10/03)
The catalytic enantioselective Diels-Alder reaction of 1,1-dicarbonylethenes 3 with cyclopentadiene in the presence of Ti-TADDOLs, Mg-Ph-box and Mg-Ph-mox complexes was investigated. Although both exo- and enantioselectivity with Ti-TADDOL catalysts were
