19557-02-9

Basic information

• Product Name: cis-3-hydroxy-cyclohexanecarboxylic acid amide
• CAS NO: 19557-02-9
• Molecular Weight: 143.186
• Mol File: 19557-02-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-3-hydroxy-cyclohexanecarboxylic acid amide(CAS DataBase Reference)
• NIST Chemistry Reference: cis-3-hydroxy-cyclohexanecarboxylic acid amide(19557-02-9)
• EPA Substance Registry System: cis-3-hydroxy-cyclohexanecarboxylic acid amide(19557-02-9)

Safety Data

• Hazardous Substances Data: 19557-02-9(Hazardous Substances Data)

Upstream product

• 4350-83-8 6-oxabicyclo[3.2.1]octan-7-one 
• 6051-04-3 2-oxabicyclo[3.3.1]nonan-3-one 
• 79855-51-9 2-oxabicyclo<3.3.1>nonane-3-thione 
• 4350-83-8 6-oxa-bicyclo[3.2.1]octan-7-one 

Relevant articles and documents

Pyrolysis of the Tosylhydrazone Sodium Salts of Two Bicyclic Lactones

Lactone tosylhydrazone sodium salt 17a was prepared from lactone 10 by way of thionolactone 14.The tert-butyl homologue 17b was available by way of hydroxy nitrile 5.Pyrolysis of these salts led to enol ethers 18a,b and the ring-contracted ketones 19a,b.Together with earlier work, our results suggest that biradical 3 is probably an intermediate in conversion of alkoxycarbene 2 to ketone 4 and that the activation energy for this biradical coupling is ca. 2-3 kcal/mol.