195608-71-0Relevant academic research and scientific papers
Photochemical functionalizations of C60 with phenylpolysilanes
Kusukawa, Takahiro,Ando, Wataru
, p. 11 - 22 (2007/10/03)
Photolyses of tert-butyl substituted disilanes 1a-1c, and 1i with C60 result in the formation of 1,16-adduct 2 through silyl radical addition to fullerene. The unusual products, 3, 5, 6 and 7 where the silyl and phenyl groups attached on 1,2-positions of fullerene are also obtained from the reaction of 1d-g and 4. The structures of all these compounds were determined by one- and two-dimensional NMR techniques.
