195864-43-8Relevant academic research and scientific papers
Phosphorus monoxide as a terminal ligand
Johnson, Marc J. A.,Odom, Aaron L.,Cummins, Christopher C.
, p. 1523 - 1524 (1997)
Dimethyldioxirane oxidation of phosphide PMo[N(R)Ar]3 [R = C(CD3)2Me, Ar = C6H3Me2-3,5] efficiently provides (OP)Mo[N(R)Ar]3, a complex shown by X-ray crystallography to contain a terminal phosphorus monoxide ligand, and which reacts with dimethylzirconocene to give addition of a Zr-Me bond across the phosphoryl moiety.
