196101-18-5Relevant academic research and scientific papers
Some single electron-transfer reactions of arylimines
Brown, David W.,Lindquist, Monika,Mahon, Mary F.,Malm, Bengt,Nilsson, Goeran N.,Ninan, Aleyamma,Sainsbury, Malcolm,Westerlund, Christer
, p. 2337 - 2343 (2007/10/03)
When treated with suitable alkyllithiums, arylimines may undergo single electron-transfer and conjugative substitution in the aryl ring, as well as nucleophilic addition to the imine bond. Multiple substitutions by tert-butyl radicals are noted, giving rise to rearranged and oxidized products, including cycloadducts.
