196409-49-1

Upstream product

• 196409-38-8 (2S)-2-hydroxy-N-methoxy-N-methyl-3-[(R)-p-tolylsulfinyl]propanamide 
• 196409-37-7 (R)-N-methoxy-N-methyl-2-oxo-3-(p-tolylsulfinyl)propanamide 
• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 100-58-3 phenylmagnesium bromide 
• 196409-39-9 (S)-2-(tert-Butyl-dimethyl-silanyloxy)-N-methoxy-N-methyl-3-((R)-toluene-4-sulfinyl)-propionamide 

Downstream Products

• 221638-04-6 (1S,2S)-2-(tert-Butyl-dimethyl-silanyloxy)-1-phenyl-3-((R)-toluene-4-sulfinyl)-propan-1-ol 
• 221638-08-0 (1R,2S)-2-(tert-Butyl-dimethyl-silanyloxy)-1-phenyl-3-((R)-toluene-4-sulfinyl)-propan-1-ol 
• 5650-40-8 (R)-2-hydroxy-1-phenylpropan-1-one 

Relevant academic research and scientific papers

Stereoselective sulfoxide directed reduction of 1,2-diketo-derivatives to enantiomerically pure syn and anti 1,2-diols

A new route to enantiopure syn and anti 1,2-diols is described from oxalyl-di-(N-methyl-N-methoxyamide) via the corresponding β-ketosulfoxide. This is the first report of the stereoselective reduction of a γ-keto-β-hydroxysulfoxide.