19646-38-9Relevant academic research and scientific papers
CARBALDEHYDE OXIMES AS BUTYRYLCHOLINESTERASE REACTIVATORS
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, (2022/02/07)
The present invention relates to compounds for their use in the reactivation of butyrylcholinesterase. Such compounds are useful in the treatment or prevention of the intoxication with at least one organophosphorus nerve agent. The invention also relates
Rate constants for the β-elimination of tosyl radical from a variety of substituted carbon-centered radicals
Timokhin, Vitaliy I.,Gastaldi, Stephane,Bertrand, Michele P.,Chatgilialoglu, Chryssostomos
, p. 3532 - 3537 (2007/10/03)
The rate constants for the β-elimination of tosyl radical (Ts?) from a series of carbon-centered radicals have been determined by using the radical clock methodology. Depending on the substituents R in Ts-CH2-CH(?)R radicals, the rate constants at 293 K vary by more than 2 orders of magnitude in the range of 103-106 s-1. The lowest values were found for the 2-naphthyl and carbamoyl substituents, whereas the benzyl substituent is located at the other extremity. The effect of the substituent upon the stabilization of the starting radical exerts a predominant influence in this reaction in decreasing the rate of fragmentation.
GENERATION OF SULPHONYL RADICALS FROM SULPHONATE ESTERS
Culshaw, Peter N.,Walton, John C.
, p. 2457 - 2460 (2007/10/02)
Alkane alkylsulphonates and arylsulphonates are useful sources of sulphonyl radicals on treatment with organotin radicals.EPR spectra of the adduct radicals from CH3SO2* and alkenes containing donor substituents were observed.
