196494-09-4

Basic information

• Product Name: {2,3-Bis-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-propoxymethyl}-benzene
• Synonyms: {2,3-Bis-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-propoxymethyl}-benzene
• CAS NO: 196494-09-4
• Molecular Weight: 466.852
• Mol File: 196494-09-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {2,3-Bis-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-propoxymethyl}-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: {2,3-Bis-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-propoxymethyl}-benzene(196494-09-4)
• EPA Substance Registry System: {2,3-Bis-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-propoxymethyl}-benzene(196494-09-4)

Safety Data

• Hazardous Substances Data: 196494-09-4(Hazardous Substances Data)

Upstream product

• 15028-56-5 4-(benzyloxymethyl)-2,2-dimethyl-1,3-dioxolane 
• 100-44-7 benzyl chloride 
• 13071-59-5 3-benzyloxypropan-1,2-diol 
• 67373-56-2 chlorodimethyl(1,1,2-trimethylpropyl)silane 

Downstream Products

• 103397-09-7 1-O-benzyl-2,3-di-O-dodecanoyl-rac-glycerol 

Relevant articles and documents

Synthesis of esters from silyl ethers and acyl chlorides: Catalysis by quaternary ammonium chlorides

The formation of esters from silyl ethers and acyl chlorides is catalysed by quaternary ammonium chlorides, the other halide ions being less efficient. Evidence for the intermediacy of the alcohol formed by protodesilylation of the silyl ether is presented. Excellent regioselectivities (>99%) were obtained in the monoacylations of the bis-silyl ether 3 made from 1-?-benzylglycerol. Acta Chemica Scandinavica 1997.