196501-87-8

Upstream product

• 108-86-1 bromobenzene 
• 135-19-3 β-naphthol 
• 591-50-4 iodobenzene 
• 186465-05-4 1-([1,1'-biphenyl]-2-yl)-2-methoxynaphthalene 
• 3401-47-6 1-bromo-2-methoxynaphthalene 
• 573-97-7 1-bromo-2-naphthol 
• 10124-81-9 Lithium β-naphtholate 
• 218961-91-2 Carbonic acid 1-biphenyl-2-yl-naphthalen-2-yl ester (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 

Downstream Products

• 218961-92-3 1-Biphenyl-2-yl-2-methoxymethoxy-naphthalene 
• 218961-93-4 4-Biphenyl-2-yl-3-methoxymethoxy-naphthalene-2-carbaldehyde 

Relevant academic research and scientific papers

Palladium-catalyzed regioselective mono- and diarylation reactions of 2-phenylphenols and naphthols with aryl halides

Not only monoarylation but also diarylation of 2-phenylphenols with aryl iodides proceeds effectively and regioselectively when a palladium catalyst and an appropriate base are employed. The products are 1,2-diphenyl- and 1,2,3-triphenylbenzene derivative

Regioselective Arylation Reactions of Biphenyl-2-ols, Naphthols, and Benzylic Compounds with Aryl Halides under Palladium Catalysis

Biphenyl-2-ols undergo regioselective mono- and diarylation upon a treatment with aryl iodides in the presence of a palladium catalyst in DMF using Cs2CO3 as a base to produce 1,1′ : 2′,1″-terphenyl-2-ol and 2′,6′-diphenylbiphenyl-2-ol and their derivatives. The reaction of 1-naphthol selectively occurs at its 8-position to give 8-aryl-1-naphthols. In the reaction of 2-naphthol with aryl bromides, diarylated compounds, 1-(2-arylphenyl)-2-naphthols, are formed as the single major products. Under similar conditions, benzyl ketones, phenylacetonitrile, and methyl phenylacetate are arylated at their benzylic position.

Catalytic and highly enantioselective aziridination of styrene derivatives

Highly enantioselective catalytic aziridination of styrene derivatives was realized by using the newly designed (salen)manganese(III) complex as a catalyst.