19656-74-7

Basic information

• Product Name: 1,2-Di-tert-butyl-3H-diazirine-3-one
• Synonyms: 1,2-Di-tert-butyl-3H-diazirine-3-one;1,2-Di-tert-butyldiaziridin-3-one
• CAS NO: 19656-74-7
• Molecular Formula: C₉H₁₈N₂O
• Molecular Weight: 170.25
• Mol File: 19656-74-7.mol

Chemical Properties

• Boiling Point: 60-64 °C(Press: 7 Torr)
• Appearance: /
• Density: 1.035±0.06 g/cm3(Predicted)
• PKA: -3.34±0.20(Predicted)
• CAS DataBase Reference: 1,2-Di-tert-butyl-3H-diazirine-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Di-tert-butyl-3H-diazirine-3-one(19656-74-7)
• EPA Substance Registry System: 1,2-Di-tert-butyl-3H-diazirine-3-one(19656-74-7)

Safety Data

• Hazardous Substances Data: 19656-74-7(Hazardous Substances Data)

Upstream product

• 5336-24-3 1,3-di-tert-butylurea 

Downstream Products

• 5336-24-3 1,3-di-tert-butylurea 
• 30885-14-4 N,N'-di-tert-butyldiazetidinedione 
• 954117-64-7 C₂₀H₃₀N₂O 
• 944583-72-6 C₁₉H₂₈N₂O 
• 1156454-52-2 C₂₈H₃₄F₆N₂O₂ 
• 1156454-53-3 C₂₈H₃₄F₆N₂O₂ 
• 1156454-42-0 C₁₉H₃₀N₂O 
• 1156454-43-1 C₁₈H₂₇ClN₂O 
• 1156454-45-3 C₁₉H₃₀N₂O 
• 1156454-49-7 C₁₉H₂₈N₂O₃ 

Relevant articles and documents

N -tert-butyl -2 -phenylindole derivative Preparation method and application

The invention belongs to the technical field of organic synthesis, and particularly relates to N - tert-butyl -2 -phenyl indole derivatives as well as a preparation method and application thereof. The preparation method comprises the following steps: (Z)-1 - bromo -1 - phenyl -2 - styrene derivative, N, N - di-tert-butyl diazepinone, palladium catalyst, monophosphine ligand, hydrocarbon activator, base and first solvent, and N -tert-butyl -2 -aryl indole derivatives which can synthesize substituent type diversity, and the prepared N -tert-butyl -2 -aryl indole derivative can be used for preparing biologically active molecules N -2 .

5, 10-dihydroindolo [3, 2-b] indole derivative and synthesis method and application thereof

The invention discloses a synthesis method of a 5, 10-dihydroindolo [3, 2-b] indole derivative, the method comprises the following steps: mixing a 2-((2-halogen phenyl) ethynyl)-N, N-dimethylaniline derivative (II), N, N-di-tert-butyl diazacycloketone (III), a palladium catalyst, a monophosphine ligand, alkali and a first organic solvent, and carrying out a diamidation reaction under the protection of inert gas to realize the synthesis of the 5, 10-dihydroindolo [3, 2-b] indole derivative(I). The method is easy to operate, mild in reaction condition and high in reaction yield, and the synthesized 5, 10-dihydroindolo [3, 2-b] indole derivative can be used for preparing an organic light-emitting device.

Catalytic asymmetric allylic and homoallylic diamination of terminal olefins via formal C-H activation

This paper describes a catalytic asymmetric diamination process for terminal olefins at allylic and homoallylic carbons via formal C-H activation using di-tert-butyldiaziridinone as nitrogen source with a catalyst generated from Pd2(dba)3 and chiral phosphorus amidite ligand. A wide variety of readily available terminal olefins can be effectively diaminated in good yields with high regio-, diastereo-, and enantioselectivities. Copyright