19656-91-8Relevant articles and documents
Garin
, p. 2830 (1970)
Baldwin,Gano
, p. 3506,3510 (1967)
Cohalogenation of alkenes in ethylene oxide: Efficient methodology for the preparation of allyl vinyl ether precursors of γ,δ-unsaturated aldehydes
Dulcere,Rodriguez
, p. 399 - 405 (2007/10/02)
An investigation of the cohalogenation-dehydrohalogenation sequence as a method for the preparation of allyl vinyl ethers from simple olefins has been performed. Alkenes 1a-k react with bromide or chloride in the presence of ethylene oxide at -80°C to for
PHOTOLYSIS OF THE AZOALKANE 2,3-DIAZATRICYCLO4,9>NON-2-ENE: DIRECT OBSERVATION OF 4-CYCLOHEXENYLDIAZOMETHANE
Adam, Waldemar,Carballeira, Nestor,Gillaspey, William D.
, p. 5473 - 5476 (2007/10/02)
Besides denitrogenation to the tricycloalkane 8, the photolysis of azoalkane 3 affords the diazoalkane 4, which serves as precursor to the minor hydrocarbon products 9, 10 and 11; irradiation of azoalkane 3 with the 333.6 nm line of an 18-W argon ion laser was essential to obtain preparative quantities of diazoalkane 4 for its detection and identification.