196793-69-8

Basic information

• Product Name: (η5-4-Ph-7-Ph-C9H5)TiCl3
• CAS NO: 196793-69-8
• Molecular Weight: 421.589
• Mol File: 196793-69-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (η5-4-Ph-7-Ph-C9H5)TiCl3(CAS DataBase Reference)
• NIST Chemistry Reference: (η5-4-Ph-7-Ph-C9H5)TiCl3(196793-69-8)
• EPA Substance Registry System: (η5-4-Ph-7-Ph-C9H5)TiCl3(196793-69-8)

Safety Data

• Hazardous Substances Data: 196793-69-8(Hazardous Substances Data)

Upstream product

• 951152-39-9 C₂₁H₁₅Si(CH₃)3 
• 7550-45-0 titanium tetrachloride 

Relevant articles and documents

3,4-, 4,7- and 1,4,7-Substituted indenyl-TiCl3 complexes: Synthesis and comparison of substituent effects

Me3Si-substituted indenes of type 1-SiMe3-3,4- (CH2)3C9H5 (9), 1-SiMe 3-4-R-7-R′C9H5 (11a, R = R′ = Me; 11b, R = R′ = Ph; 11c, R = Me, R′ = Ph) and 1,1′-(SiMe 3)2-4,7-Me2C9H4 (12) were synthesised as precursors for piano-stool type halfsandwich indenyl-titanium trichloride complexes. Treatment of 9, 11, and 12 with equimolar amounts of TiCU gives the complexes (η5-3,4-(CH2)3C 9H5)TiCl3 (13), (η5-4-R-7- R′C9H5)TiCl3 (14a, R = R′ = Me; 14b, R = R′ = Ph; 14c, R = Me, R′ = Ph), and (η5-1- SiMe3-4,7-Me2C9H4)TiCl3 (15), respectively, with liberation of Me3SiCl. Detailed UV/vis spectroscopic and cyclic voltammetric studies were carried out which allow a comparison of substituent effects in 13-15.