196801-71-5Relevant academic research and scientific papers
Copper-catalyzed allylations of o-vinylbenzylzirconocene intermediate
Ikeuchi, Yutaka,Taguchi, Takeo,Hanzawa, Yuji
, p. 3717 - 3720 (2007/10/03)
Benzylzirconocene intermediate, which was readily prepared by the reaction of o-alkoxymethylstyrene with 'Cp2Zr' under mild conditions, reacted with allylic halides or phosphates in the presence of catalytic amount of CuCl to give allylated pro
Organolithium additions to styrene derivatives, Part IV: Tandem intermolecular-intramolecular carbolithiation as a new route to tetralins
Wei, Xudong,Taylor, Richard J. K.
, p. 6467 - 6470 (2007/10/03)
Styrenes bearing unsaturated side chains at the 2-position undergo regioselective carbolithiation of the styrene unit followed by 6-exo-trig or 6-exo-dig cyclisation to produce 1,2- disubstituted tetralins or their unsaturated analogues.
Unprecedented reactions of substituted styrene derivatives with zirconocene-(1-butene) complex
Hanzawa, Yuji,Ikeuchi, Yutaka,Nakamura, Takanori,Taguchi, Takeo
, p. 6503 - 6506 (2007/10/02)
Reactions of alkoxymethyl substituted styrene derivatives with a stoichiometric and/or catalytic amount of zirconocene-(1-butene) complex ('Cp2Zr') causes an unexpected zirconocene insertion into benzylic position and/or homolytic coupling reaction of the styrene derivatives.
