1969-47-7Relevant academic research and scientific papers
Nucleophilic imidoesterification of dicarbonyl compounds with cyanatobenzenes through CC bond formation
Ma, Hang,He, Yang,Huang, Ruo-Feng,Zhang, Xiao-Hui,Pan, Jing,Li, Jia-Qiang,He, Chao,Ling, Xue-Ge,Wang, Xuan-Lun,Xiong, Yan
, p. 1327 - 1330 (2014)
Under neat conditions, an efficient method for synthesis of imidoesters has been developed using cyanatobenzenes and dicarbonyl compounds. Nucleophilic addition spontaneously occurred between the two kinds of materials at room temperature with yields of up to 90%. A mechanism directed towards to the imidoester formation has been proposed.
Oxidative rearrangement strategy for synthesis of 2,4,5-trisubstituted oxazoles utilizing hypervalent iodine reagent
Liu, Qing,Zhang, Xiaohui,He, Yang,Hussain, Muhammad Ijaz,Hu, Wen,Xiong, Yan,Zhu, Xiangming
supporting information, p. 5749 - 5753 (2016/08/30)
Hypervalent iodine (III)-intermediated direct oxidative rearrangement of 3-hydroxybut-2-enimidates affording oxazoles under mild conditions has been developed. This protocol provides a new methodology to the synthesis of compounds containing oxazole structure.
