197005-23-5

Upstream product

• 108-98-5 thiophenol 
• 39698-00-5 acetyl 2,4,6-tri-O-acetyl-3-O-allyl-β-D-glucopyranoside 
• 197005-22-4 phenyl 2,4,6-tri-O-acetyl-3-O-allyl-1-thio-β-D-glucopyranoside 

Downstream Products

• 556039-05-5 phenyl 3-O-allyl-4,6-O-p-methoxybenzylidene-1-thio-β-D-glucopyranoside 
• 556039-04-4 N-Benzyl-succinamic acid (2R,3R,4R,5R,6S)-4-allyloxy-5-hydroxy-3-(4-methoxy-benzyloxy)-6-phenylsulfanyl-tetrahydro-pyran-2-ylmethyl ester 
• 556039-09-9 Succinic acid mono-[(2R,3R,4R,5R,6S)-4-allyloxy-5-hydroxy-3-(4-methoxy-benzyloxy)-6-phenylsulfanyl-tetrahydro-pyran-2-ylmethyl] ester 
• 556039-02-2 phenyl 3-O-allyl-4-O-p-methoxybenzyl-1-thio-β-D-glucopyranoside 

Relevant academic research and scientific papers

D-glucose as a regioselectively addressable scaffold for combinatorial chemistry on solid phase

D-Glucose derivatives bearing an anomeric thiophenyl group and orthogonally protections on secondary hydroxyl groups were linked to solid supports (PS/DV polymer, tentagel resin) through an ester bond on C-6. It was investigated the possibility to remove orthogonally protecting groups and functionalize selectively the free hydroxyls groups and the anomeric carbon of sugars in solid phase.