197371-34-9Relevant academic research and scientific papers
Reaction of thiophenol with glucal epoxides: X-ray structure of 3,4,6-tri-O-tert-butyldimethylsilyl-1-S-phenyl-1-thio-α-D-glucopyranoside
Walford, Caroline,Jackson, Richard F. W.,Rees, Nicholas H.,Clegg, William,Heath, Sarah L.
, p. 1855 - 1856 (1997)
The reaction of the tert-butyldimethylsilyl protected glucal epoxide 1 with thiophenol under a variety of conditions gives three distinct adducts, including the α-phenylthioglycoside 2a, which exists both in solution and in the solid state in 1
Studies on the stereoselective synthesis of C-allyl glycosides
McGarvey, Glenn J.,Leclair, Christopher A.,Schmidtmann, Bahar A.
supporting information; experimental part, p. 4727 - 4730 (2009/06/05)
(Equation Presented) An investigation was carried out to explore the use of sulfoxide donors as common precursors to stereoisomeric C-glycoconjugates of glycoprotein and glycolipid tumor antigens. A study focusing on the effects of reaction conditions and substrate structure on the stereoselectivity of allylation was carried out. Although conditions were realized to selectively afford α-allylation products in good to excellent yields, the search for conditions favoring β-selectivity proved less successful.
