197389-47-2

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Basic information

Product Name: (4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT
Synonyms: (4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT;(4R,5R)-(-)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM (IV) DICHLORIDE ACETONITRILE;(4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV)dichlorideacetonitrileadduct;(4R,5R)-(-)-2,2-DiMethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-diMethanolatotitaniuM(IV) dichloride acetonitrile adduct;Dichloro[[(4R,5S)-2,2-dimethyl-1,3-dioxolane-4,5-diyl]bis(di-1-naphthylmethanolato)]titanium;[(4R,5R)-5-[hydroxy(dinaphthalen-1-yl)methyl]-2,2-dimethyl-1,3-oxazolidin-4-yl]-dinaphthalen-1-ylmethanol;'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV) dichloride acetonitrile adduct
CAS NO:197389-47-2
Molecular Formula: C49H40Cl2N2O3Ti
Molecular Weight: 823.63
EINECS: N/A
Product Categories: Chiral Oxygen;TADDOL Series
Mol File: 197389-47-2.mol
Article Data: 0

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: yellow/Powder
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
Sensitive: air sensitive, moisture sensitiv
CAS DataBase Reference: (4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT(CAS DataBase Reference)
NIST Chemistry Reference: (4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT(197389-47-2)
EPA Substance Registry System: (4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT(197389-47-2)

Safety Data

Hazard Codes: N/A
Statements: 20/21/22-36/37/38
Safety Statements: 26-36/37/39
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 197389-47-2(Hazardous Substances Data)

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(4R,5R)-(-)-2,2-DiMethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-diMethanolatotitaniuM(IV) dichloride acetonitrile adduct
Cas No: 197389-47-2
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Antimex Chemical Limied
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(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(NAPHTHALEN-1-YL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCTCAS
Cas No: 197389-47-2
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Hangzhou Fandachem Co.,Ltd
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(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT
Cas No: 197389-47-2
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ZHEJIANG JIUZHOU CHEM CO.,LTD
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(4R,5R)-(-)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRA(1-NAPHTHYL)-1, 3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM (IV) DICHLORIDE ACETONITRILE ADDUCT
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(4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolato titanium(IV) dichloride acetonitrile adduct
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Cerametek Materials（ShenZhen）Co., Ltd.
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Titanium,dichloro[2,2-dimethyl-a,a,a',a'-tetra-1-naphthalenyl-1,3-dioxolane-4,5-dimethanolato(2-)-kO4,kO5]-, [T-4-(4R-trans)]- (9CI)
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Shanghai Mintchem Development ., Ltd
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(4R,5R)-(-)-2,2-Dimethyl-α;,α;,α;',α;'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV) dichloride acetonitrile adduct
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Strem Chemicals, Inc.
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197389-47-2 Usage

Reaction

Catalyst used in the enantioselective fluorination of β-ketoesters. Versatile catalyst used in the enantioselective 1,2 and 1,4 additions to carbonyl compounds, transfer of allyl groups to aldehydes, cycloadditions and others.

Check Digit Verification of cas no

The CAS Registry Mumber 197389-47-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,9,7,3,8 and 9 respectively; the second part has 2 digits, 4 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 197389-47:
(8*1)+(7*9)+(6*7)+(5*3)+(4*8)+(3*9)+(2*4)+(1*7)=202
202 % 10 = 2
So 197389-47-2 is a valid CAS Registry Number.

197389-47-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name	acetonitrile,dichlorotitanium,[(4R,5R)-5-[hydroxy(dinaphthalen-1-yl)methyl]-2,2-dimethyl-1,3-oxazolidin-4-yl]-dinaphthalen-1-ylmethanol

1.2 Other means of identification

Product number	-
Other names	-

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:197389-47-2 SDS

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