197649-30-2Relevant academic research and scientific papers
Studies on the synthesis of two tetrasaccharides and the reactivity difference between them
Zhu, Xiao-Xiang,Cai, Meng-Shen,Zhou, Rou-Li
, p. 261 - 266 (2007/10/03)
Studies on the reactivity of two synthetic tetrasaccharides as glycosyl acceptors showed that condensation of the methyl α-glycoside with a disaccharide donor afforded a hexasaccharide, but condensation of the methyl β-glycoside with the disaccharide did not yield the corresponding hexasaccharide under the same conditions. A combination of theoretical results and 2D NMR indicated that the reactivity difference between the methyl α-glycoside and the methyl β-glycoside was determined mainly by steric effects.
