19774-38-0

Basic information

• Product Name: 1,3-Butadiene, 1-methoxy-, (Z)-
• Synonyms: cis-1-methoxy-1,3-butadiene;cis-1-Methoxy-1,3-butadien;1-methoxy-buta-1,3-diene;(Z)-1-Methoxy-1,3-butadiene;(Z)-1-Methoxy-buta-1,3-diene;cis-1-methoxybutadiene;1-methoxybuta-1,3-diene
• CAS NO: 19774-38-0
• Molecular Formula: C5H8O
• Molecular Weight: 84.1179
• Mol File: 19774-38-0.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 35 °C (160 mmHg)
• CAS DataBase Reference: 1,3-Butadiene, 1-methoxy-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Butadiene, 1-methoxy-, (Z)-(19774-38-0)
• EPA Substance Registry System: 1,3-Butadiene, 1-methoxy-, (Z)-(19774-38-0)

Safety Data

• Hazardous Substances Data: 19774-38-0(Hazardous Substances Data)

Upstream product

• 54477-71-3 {(P(CH₂CH₂P(C₆H₅)2)3)FeH(N₂)}⁽¹⁺⁾*{B(C₆H₅)4}^(1-)={(P(CH₂CH₂P(C₆H₅)2)3)FeH(N₂)}{B(C₆H₅)4} 
• 2798-73-4 (Z)-1-methoxybut-1-en-3-yne 
• 22805-71-6 (E)-1,4-dimethoxy-2-butene 
• 41649-14-3 cis-1,4-dimethoxy-2-butene 

Downstream Products

• 123-73-9 trans-Crotonaldehyde 
• 7319-38-2 3-butenal 
• 105435-38-9 N-[1-(6-Methoxy-3,6-dihydro-2H-pyran-2-yl)-2-phenyl-ethyl]-4-methyl-benzenesulfonamide 
• 105435-34-5 N-[1-(6-Methoxy-3,6-dihydro-2H-pyran-2-yl)-ethyl]-4-methyl-benzenesulfonamide 
• 74503-37-0 3-Methoxy-4-cyclohexen-1,1,2,2-tetracarbonitril 

Relevant articles and documents

Mixed metal bases as promoters of 1,4-eliminations

When treated with the LIDAKOR mixture, allyl type ethers very readily undergo 1,4-elimination to afford conjugated dienes (3 - 73). In typical cases, the reaction is brought about stereo- and regioselectively (2 and 7, respectively). Under suitable conditions, lithium dimethylamide or even lithium diisopropylamide adds to the dienes generated in situ thus leading to a variety of new allyl amines (5-8).