1981-38-0Relevant articles and documents
The effect of electron-withdrawing substituents in asymmetric anthracene derivative semiconductors
Liu, Si,Zheng, Lei,Chen, Mingxi,Sun, Yajing,Wang, Peng,Li, Shuyu,Wu, Hongnan,Zhang, Xiaotao,Hu, Wenping
, p. 4217 - 4222 (2021)
Three anthracene derivatives, referred to as 2-phenyl anthracene (Ph-Ant), 2-thiazole anthracene (TZ-Ant), and 2-pentafluorophenyl anthracene (F5Ph-Ant), were designed and synthesized to reveal the effects of the electron-withdrawing substituents on the molecular packing structure and photoelectric properties of the anthracene core. As the electron-withdrawing abilities of the substituents increased, the molecular structures of the three semiconductors showed a progressive deterioration in intermolecular interactions and molecular accumulation, and the photoelectric properties became worse. Interestingly, the energy levels of the three semiconductors showed gradually decreasing changes with an enhancement of the electron-withdrawing abilities of the substituents, indicating a possible strategy for fabricating n-type anthracene derivative semiconductor materials.
A General Method for Growing Two-Dimensional Crystals of Organic Semiconductors by “Solution Epitaxy”
Xu, Chunhui,He, Ping,Liu, Jie,Cui, Ajuan,Dong, Huanli,Zhen, Yonggang,Chen, Wei,Hu, Wenping
, p. 9519 - 9523 (2016)
Two-dimensional (2D) crystals of organic semiconductors (2DCOS) have attracted attention for large-area and low-cost flexible optoelectronics. However, growing large 2DCOS in controllable ways and transferring them onto technologically important substrates, remain key challenges. Herein we report a facile, general, and effective method to grow 2DCOS up to centimeter size which can be transferred to any substrate efficiently. The method named “solution epitaxy” involves two steps. The first is to self-assemble micrometer-sized 2DCOS on water surface. The second is epitaxial growth of them into millimeter or centimeter sized 2DCOS with thickness of several molecular layers. The general applicability of this method for the growth of 2DCOS is demonstrated by nine organic semiconductors with different molecular structures. Organic field-effect transistors (OFETs) based on the 2DCOS demonstrated high performance, confirming the high quality of the 2DCOS.
COMPOUND AND ORGANIC LIGHT EMITTING DEVICE COMPRISING THE SAME
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Paragraph 0379-0382, (2021/08/05)
The present specification provides a compound represented by chemical formula 1 and an organic light emitting device including the same. The compound described in the present specification can be used as a material for an organic material layer of the organic light emitting device. In the case of manufacturing the organic light emitting device including the compound according to an exemplary embodiment of the present invention, the organic light emitting device having excellent luminous efficiency, low driving voltage, high efficiency, and long lifespan can be obtained.