19850-38-5Relevant academic research and scientific papers
Synthesis and crystal structures of two schiff bases of 2-(methylthio)aniline with halogenated salicylaldehydes
Hamaker, Christopher G.,Maryashina, Oksana S.,Daley, Dana K.,Wadler, Andrew L.
, p. 34 - 39 (2010)
The crystal structures of the new compounds 5-bromo-N-[2-(methylthio)- phenyl]salicylaldimine (1), and 3,5-dichloro-N-[2-(methylthio)phenyl] salicylaldimine (2) were obtained by single crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic space group P21/c with a = 14.1479(14) A, b = 5.3058(3) A, c = 19.104(3) A; β = 106.218(10)°; and Z = 4. Compound 2 crystallizes in the triclinic space group P1 with a = 11.2249(10) A, b = 13.863(2) A, c = 13.9055(9) A; and α = 99.378(15)°, β = 102.866(7)°, γ = 91.375(11)°; and Z = 6. Details of the synthesis, structures, and spectroscopic properties of the new compounds are discussed.
