198546-11-1

Basic information

• Product Name: (1S,2R,6R)-1-hydroxy-3-(3-m-methoxyphenylpropyl)-6,8,8-trimethyl-2-oxabicyclo[4,3,0]nonan-7-one
• CAS NO: 198546-11-1
• Molecular Weight: 346.467
• Mol File: 198546-11-1.mol

Chemical Properties

• CAS DataBase Reference: (1S,2R,6R)-1-hydroxy-3-(3-m-methoxyphenylpropyl)-6,8,8-trimethyl-2-oxabicyclo[4,3,0]nonan-7-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2R,6R)-1-hydroxy-3-(3-m-methoxyphenylpropyl)-6,8,8-trimethyl-2-oxabicyclo[4,3,0]nonan-7-one(198546-11-1)
• EPA Substance Registry System: (1S,2R,6R)-1-hydroxy-3-(3-m-methoxyphenylpropyl)-6,8,8-trimethyl-2-oxabicyclo[4,3,0]nonan-7-one(198546-11-1)

Safety Data

• Hazardous Substances Data: 198546-11-1(Hazardous Substances Data)

Downstream Products

• 198546-12-2 (1S,3R,6S)-3-hydroxy-3-(3-m-methoxyphenylpropyl)-6,8,8-trimethyl-2-oxabicyclo[4,3,0]nonan-7-one 
• 156412-62-3 (-)-2-(6-m-methoxyphenyl-3-oxohexyl)-2,4,4-trimethylcyclopenta-1,3-dione 

Relevant articles and documents

Microbial reduction of 2-(6-m-methoxyphenyl-3-oxohexyl)-2,4,4- trimethylcyclopenta-1,3-dione with Schizosaccharomyces pombe (NRRL Y-164)

Racemic 2-(6-m-methoxyphenyl-3-oxohexyl)-2,4,-trimethylcyclopenta- 1,3-dione 4 was resolved by reduction with Schizosaccharomyces pombe (NRRL Y-164) to give (-)-5, (+)-6, and +-7 in 37, 12, and 19% yields, respectively. Chromic acid oxidation of (-)-5 gave (+)-4 while oxidation of (+)-6 and (+)-7 gave (-)-4, respectively. Sodium borohydride reduction of (+)-4 followed by Oppenauer oxidation yielded (-)-5 and (-)7-, and the same treatment of (-)-4 yielded (+)-5 and (+)-7, respectively.