198632-63-2Relevant academic research and scientific papers
A novel luminescent iridium(I)-cadmium(II) binuclear complex displaying a long-lived metal-to-ligand charge-transfer excited state. Synthesis and structural characterisation of I(CO)2Ir(μ-Ph2Ppy)2CdI2 [Ph2Ppy = 2-(diphenylphosphino)pyridine]
Kuang, Shan-Ming,Xue, Feng,Zhang, Zheng-Zhi,Xue, Wen-Mei,Che, Chi-Ming,Mak, Thomas C. W.
, p. 3409 - 3410 (1997)
The first binuclear IrI-CdII complex to be structurally characterised, I(CO)2Ir(μ-Ph2Ppy)2CdI2 [Ph2Ppy = 2-(diphenylphosphino)pyridine], has a donor-acceptor metal-metal bond of length 2.784(1) A; at room temperature, excitation of a solid sample of the complex with UV light led to a red emission at 739 nm with a lifetime of 6.48 μs that presumably originates from a 3MLCT excited state.
