198640-90-3

Upstream product

• 198640-87-8 2-[((2R,3R,4S,5R,6R)-3,4,5-Tris-methanesulfonyloxy-6-trityloxymethyl-tetrahydro-pyran-2-ylamino)-methylene]-malonic acid diethyl ester 
• 144310-50-9 N-(2,2-diethoxycarbonylvinyl)-6-O-trityl-β-D-glucopyranosylamine 

Relevant academic research and scientific papers

Stereoselective syntheses of 4-amino-aldoses, and chiral pyrrolidine derivatives from glycosylenamines

The stereocontrolled synthesis of N-protected 4-amino-4-deoxy-D-galacto and -L-arabino-pyranoses starting from glycosylenamines via aza- anhydropyranoses is described. The steroselective transformation of the intermediate aza-anhydropyranoses into chiral pyrrolidines is also reported.

Rearrangements of O-protected glycosylenamines. A new and efficient route for the synthesis of O-protected 4-aminoaldoses

O-Protected 4-deoxy-4-diethoxycarbonylvinylaminoaldoses with D-galacto, L-arabino and L-lyxo configurations (3) are prepared by a nucleophilic rearrangement of easily available glycosylamine derivatives.