19865-55-5

Basic information

• Product Name: N-(4-Methylbenzylidene)benzenamine N-oxide
• Synonyms: 4-Methyl-N-phenylbenzenemethanimine N-oxide;N-(4-Methylbenzylidene)aniline N-oxide;N-(4-Methylbenzylidene)benzenamine N-oxide;N-[(4-Methylphenyl)methylene]benzenamine oxide
• CAS NO: 19865-55-5
• Molecular Formula: C₁₄H₁₃NO
• Molecular Weight: 211.2591
• Mol File: 19865-55-5.mol
• Article Data: 33

Chemical Properties

• Boiling Point: 363.9°Cat760mmHg
• Flash Point: 169.2°C
• Appearance: /
• Density: 1.117g/cm³
• Vapor Pressure: 3.66E-05mmHg at 25°C
• Refractive Index: 1.641
• CAS DataBase Reference: N-(4-Methylbenzylidene)benzenamine N-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-Methylbenzylidene)benzenamine N-oxide(19865-55-5)
• EPA Substance Registry System: N-(4-Methylbenzylidene)benzenamine N-oxide(19865-55-5)

Safety Data

• Hazardous Substances Data: 19865-55-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H13NO/c1-12-7-9-13(10-8-12)11-15(16)14-5-3-2-4-6-14/h2-11H,1H3

Upstream product

• 104-87-0 4-methyl-benzaldehyde 
• 100-65-2 N-Phenylhydroxylamine 
• 2362-77-8 (4-methylbenzylidene)phenylamine 
• 586-96-9 Nitrosobenzene 
• 98-95-3 nitrobenzene 
• 99447-84-4 C₁₄H₁₃NO*C₈Cl₂N₂O₂ 
• 73662-56-3 C₁₄H₁₃NO*C₆N₄ 

Downstream Products

• 29068-12-0 2-phenyl-6a-pyrrolidin-1-yl-3-p-tolyl-hexahydro-cyclopenta[d]isoxazole 
• 29068-02-8 2-phenyl-7a-pyrrolidin-1-yl-3-p-tolyl-octahydro-benzo[d]isoxazole 
• 92234-40-7 5-(1-imidazolyl)-3-(4-methylphenyl)-2-phenylisoxazolidine 
• 136465-57-1 (3R,3aR,7aS)-5,7a-Dimethyl-2-phenyl-3-p-tolyl-2,3,3a,7a-tetrahydro-benzo[d]isoxazole-4,7-dione 
• 139174-35-9 2-phenyl-3-(4-methylphenyl)-6-oxo-8,8-dimethyl-1-oxa-2,7-diazaspiro<4,4>-non-2-ene 
• 139174-35-9 2-phenyl-3-(4-methylphenyl)-6-oxo-8,8-dimethyl-1-oxa-2,7-diazaspiro<4,4>-non-2-ene 
• 18869-29-9 (E)-4,4'-dimethylstilbene 
• 104-87-0 4-methyl-benzaldehyde 
• 99-94-5 p-Toluic acid 
• 17082-12-1 trans-azobenzene 
• 73662-64-3 2-phenyl-3-(p-tolyl)-5-(tricyanovinyl)-Δ⁴-1,2,4-oxadiazoline 
• 97585-04-1 ethyl (E)-3-(4-methylphenyl)acrylate 
• 495-48-7 azoxybenzene 
• 98056-28-1 3-anilino-1,4-diphenylbutane-1,2,4-trione 

Relevant articles and documents

LIC-KOR promoted nitrone reactivity: Stereoselective synthesis of highly conjugated imines and secondary amines

The reactivity of metalated alkoxy-1,3-dienes and α-aryl-N-phenylnitrones in the presence of LIC-KOR base, equimolar mixture of alkyllithium (LIC) and potassium alcoxides (KOR), (Schlosser, 1994) [1] has been studied. A cascade reaction involving a E1cb p

Gold-Catalyzed Oxidative Aminocyclizations of Propargyl Alcohols and Propargyl Amines to Form Two Distinct Azacyclic Products: Carbene Formation versus a 3,3-Sigmatropic Shift of an Initial Intermediate

Gold-catalyzed oxidations of propargyl alcohols with nitrones by using a P(tBu)2(o-biphenyl)Au+ catalyst, afforded bicyclic annulation products from the Mannich reactions of gold enolates. The same reactions of propargyl amines with nitrones by using the same gold catalyst gave distinct oxoarylation products. Our DFT calculations indicate that oxidation of propargyl alcohols with nitrones by using electron-rich gold catalysts lead only to gold carbenes, which can generate gold enolates or oxoarylation intermediates with enolate species having a barrier smaller than that of oxoarylation species.

Synthesis and Antimicrobial Evaluation of New Pyrrolo-isoxazolidine Derivatives

In the present study, pyrrolo-isoxazolidines 3(a-l) and 4(a-e), 4g, 4i, 4j have been synthesized by using the 1,3-dipolar cycloaddition reactions of nitrones 1(a-l) with ester substituted N-aryl maleimide (2b). These heterocycles have been obtained in cis and trans diastereomeric forms. The structures of newly synthesized heterocycles have been confirmed from their spectroscopic parameters such as IR,1H NMR,13C NMR and ESI-MS. The in vitro antimicrobial evaluation of these compounds were also investigated. Most of the prepared heterocycles showed significant antimicrobial properties. C3-phenyl substituted products exhibited the remarkable antibacterial behaviours while C3-thienyl/furyl substituted heterocycles proved themselves potent antifungal agents.