19889-37-3Relevant articles and documents
-
Roland et al.
, p. 2122 (1950)
-
Metal complex containing three different ligands
-
Paragraph 0142; 0146-0148, (2020/11/22)
A metal complex containing three different ligands is disclosed. The metal complex contains three different ligands, and can be used as a luminescent material in a luminescent layer of an organic electroluminescent device. The novel complexes not only can achieve the device performance expected to be regulated or improved by regulating substituent groups, but also can achieve the effect of effectively controlling the rise of the evaporation temperature. An electroluminescent device and a compound formulation comprising the metal complex are also disclosed.
Auxiliary-Directed C(sp3)?H Arylation by Synergistic Photoredox and Palladium Catalysis
Czyz, Milena L.,Lupton, David W.,Polyzos, Anastasios
, p. 14450 - 14453 (2017/10/07)
Herein we describe the auxiliary-directed arylation of unactivated C(sp3)?H bonds with aryldiazonium salts, which proceeds under synergistic photoredox and palladium catalysis. The site-selective arylation of aliphatic amides with α-quaternary centres is achieved with high selectivity for β-methyl C(sp3)?H bonds. This operationally simple method is compatible with carbocyclic amides, a range of aryldiazonium salts and proceeds at ambient conditions.