19890-13-2

Upstream product

• 167075-79-8 (1S,4R)-4,7,7-Trimethyl-3-oxo-2-oxa-bicyclo[2.2.1]heptane-1-carboxylic acid (1S,5R,6R)-2,7,7-trimethyl-bicyclo[3.1.1]hept-2-en-6-yl ester 
• 74033-48-0 trans-chrysanthenol 
• 473-06-3 chrysanthenone 
• 38043-83-3 (-)-trans-chrysanthenol 
• 108-24-7 acetic anhydride 
• 1185-59-7 tetraethylammonium acetate 
• 138-86-3 limonene. 

Downstream Products

• 38043-83-3 (-)-trans-chrysanthenol 

Relevant academic research and scientific papers

Oxidative esterification of alkenes via π- and σ-organopalladium complexes: New pathways for the reaction

New mechanistic data on the oxidative esterification of alkenes were obtained in the study of the reaction of Pd(II) acetate with hex-1-ene, methylcyclohex-1-ene and racemic α-pinene in a chloroform solution. High yields of unsaturated esters with terminal alcohol group were found in the oxidation of hex-1-ene, while the exocyclic methyl groups in methylcyclohex-1-ene and α-pinene remain untouched.

Synthesis of Both the Enantiomers of trans-Chrysanthenol and trans-Chrysanthenyl Acetate as the Characteristic Major Constituents of Kougiku

(-)-trans-Chrysanthenol (1) and (+)-trans-chrysanthenyl acetate (2), which had been isolated from the dried kougiku flower, and their enantiomers were synthesized via optical resolution step starting from (+)-verbenone.