19900-69-7

Usage

Uses

Used in Elastomeric Polyurethanes (PU) Industry:
4,4'-METHYLENEBIS(2,6-DIISOPROPYLANILINE) is used as a chain extender for elastomeric polyurethanes, particularly in systems cured at room temperature. Its application enhances the properties of the resulting polyurethane materials, making them more versatile and suitable for a wide range of applications.
Used in Epoxides (EP) Industry:
In the epoxides industry, 4,4'-METHYLENEBIS(2,6-DIISOPROPYLANILINE) is utilized as a curing agent. Its role in the curing process contributes to the improved performance and durability of epoxide-based products, which are widely used in various industrial applications, including adhesives, coatings, and composites.
Used in Organic Syntheses:
4,4'-METHYLENEBIS(2,6-DIISOPROPYLANILINE) also serves as an intermediate for organic syntheses, allowing the production of a variety of chemical compounds with diverse applications in different industries. Its versatility as an intermediate makes it a valuable component in the chemical manufacturing process.

Flammability and Explosibility

Nonflammable

Upstream product

• 50-00-0 formaldehyd 
• 24544-04-5 2,6-diisopropylbenzenamine 
• 67-68-5 dimethyl sulfoxide 

Downstream Products

• 1239340-38-5 4-((4E)-4-(1-(6-((E)-1-(2,6-diisopropylphenylimino)ethyl)pyridine-2-yl)ethyldeneamino)-3,5-diisopropylbenzyl)-2,6-diisopropylbenzenamine 
• 1228346-74-4 C₃₃H₄₄N₂O 
• 1443050-88-1 (4,4'-methylenebis(1-(2,6-diisopropylphenylimino)-2-(2,6-diethyl-4-methylphenylimino)acenaphthylene))Ni₂Br₄ 
• 1443050-87-0 (4,4'-methylenebis(1-(2,6-diisopropylphenylimino)-2-(2,4,6-trimethylphenylimino)acenaphthylene))Ni₂Br₄ 
• 1443050-86-9 (4,4'-methylenebis(1-(2,6-diisopropylphenylimino)-2-(2,6-diisopropylphenylimino)acenaphthylene))Ni₂Br₄ 
• 1443050-85-8 (4,4'-methylenebis(1-(2,6-diisopropylphenylimino)-2-(2,6-diethylphenylimino)acenaphthylene))Ni₂Br₄ 
• 1443050-84-7 (4,4'-methylenebis(1-(2,6-diisopropylphenylimino)-2-(2,6-dimethylphenylimino)acenaphthylene))Ni₂Br₄ 
• 1443050-80-3 4,4'-methylenebis(1-(2,6-diisopropylphenylimino)-2-(2,6-diethyl-4-methylphenylimino)acenaphthylene) 
• 1443050-79-0 4,4'-methylenebis(1-(2,6-diisopropylphenylimino)-2-(2,4,6-trimethylphenylimino)acenaphthylene) 
• 1011712-16-5 4,4'-methylenebis(1-(2,6-diisopropylphenylimino)-2-(2,6-diisopropylphenylimino)acenaphthylene) 
• 1443050-78-9 4,4'-methylenebis(1-(2,6-diisopropylphenylimino)-2-(2,6-diethylphenylimino)acenaphthylene) 
• 1011712-15-4 4,4'-methylenebis(1-(2,6-diisopropylphenylimino)-2-(2,6-dimethylphenylimino)acenaphthylene) 
• 934563-95-8 C₄₆H₆₂N₄ 
• 1296869-05-0 CH₂[C₆H₂(CH(CH₃)2)2NCHC₃N₂(CH₃)2(C₆H₅)O]2 

Relevant academic research and scientific papers

Highly regioselective para-methylthiolation/bridging methylenation of arylamines promoted by NH4I

Aryl methyl thioethers and methylene-bridged arylamines were synthesized via highly regioselective para-methylthiolation/bridging methylenation of arylamines using DMSO as the methylthio or methylene source in the presence of NH4I under metal-free conditions. For the substrates with both electron-donating and electron-withdrawing substituents, the reaction proceeded smoothly and gave moderate to good yields.

TRANSITION METAL COMPOUNDS FOR OLEFIN POLYMERIZATION AND OLIGOMERIZATION

This invention relates to new transition metal catalyst compounds represented by the formula (I): where: M and M' are, independently, a group 8, 9, 10 or 11 transition metal, preferably Ni, Co, Pd, Cu or Fe; each R group is, independently, is, hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent R groups may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; R' is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent R groups may join together with R' to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; each X group is, independently, is, hydrogen, a halogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted sililcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent X groups may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; m and m’ are, independently, 0, 1, 2, or 3; z and z’ are, independently, 0, 1, 2, or 3; N is nitrogen; Q is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents; Q’ is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl or substituted germylcarbyl substituents; and L is a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituent.