199116-18-2Relevant academic research and scientific papers
Totally Stereoselective Synthesis of 1,3-Disaccharides through Diels-Alder Reactions
Bartolozzi, Alessandra,Pacciani, Stefania,Benvenuti, Cecilia,Cacciarini, Martina,Liguori, Francesca,Menichetti, Stefano,Nativi, Cristina
, p. 8529 - 8533 (2007/10/03)
A nonclassical, totally stereoselective synthesis of orthogonally protected 1,3-disaccharides is reported. Enantiomerically pure β-keto-δ-lactones, efficiently obtained from glucal and galactal, are transformed into electron-poor heterodienes and chemo-,
A highly convergent total synthetic route to glycopeptides carrying a high-mannose core pentasaccharide domain N-linked to a natural peptide motif
Danishefsky, Samuel J.,Hu, Shuanghua,Cirillo, Pier F.,Eckhardt, Matthias,Seeberger, Peter H.
, p. 1617 - 1628 (2007/10/03)
N-Linked glycopeptides were synthesized by condensation of a high-mannose anomeric amine bearing a pentasaccharide with aspartic-acid-containing tri- and pentapeptides through the agency of IIDQ. The pentasaccharide portion, corresponding to the 'core' re
