199273-93-3Relevant academic research and scientific papers
Drawbacks Arising from the High Steric Congestion in the Synthesis of New Dendritic Polyalkylaromatic Polyradicals
Ruiz-Molina, Daniel,Veciana, Jaume,Palacio, Fernando,Rovira, Concepcio
, p. 9009 - 9017 (2007/10/03)
The synthesis of the highly strained tris(α,α-bis(pentachlorophenyl)-2,4,5,6-tetrachlorotolyl)methane (8), which is the precursor of the first generation of the polyradical series III, has been achieved by exhaustive chlorination of compound 11. Stepwise
Synthesis of a Sterically Congested Highly Chlorinated Triphenylmethane Dendrimer
Ruiz,Veciana,Rovira
, p. 1205 - 1207 (2007/10/03)
The synthesis of the highly congested dendrimer tris(α,α-bispentachlorophenyl-2,4,5,6-tetrachlorotolyl)methane (1) is not feasible by a stepwise divergent synthesis due to the large steric impedance. Its synthesis has been achieved by exhaustive chlorinat
