199274-52-7Relevant academic research and scientific papers
[Ru(η5-C5Me5)(Me2NCH 2CH2NMe2)]+, a stable 16-eleetron complex. Reaction with dioxygen and formation of a monomeric hydroxoruthenium tetramethylfulvene complex
Gemel, Christian,Mereiter, Kurt,Schmid, Roland,Kirchner, Karl
, p. 5601 - 5603 (2008/10/08)
NaBAr′4 (Ar′ = 3,5-C6H3(CF3)2) abstracts chloride from Ru(η5-C5Me5)(Me2NCH 2CH2NMe2)Cl (1) in Et2O to give the stable cationic 16e complex [Ru(η5-C5Me5)(Me2NCH 2CH2NMe2)]BAr′4 (2). Exposure of a Et2O solution of 2 to air at room temperature yields the novel monomeric hydroxotetramethylfulvene complex [Ru(η6-C5Me4CH2)(Me 2NCH2CH2NMe2)(OH)]BAr′ 4 (4).
