199330-34-2Relevant academic research and scientific papers
Neutral bis (carbene) platinum (II) complexes
Zhang, Shi-Wei,Ishii, Rie,Motoori, Fumie,Tanaka, Takanori,Takai, Yoshio,Sawada, Masami,Takahashi, Shigetoshi
, p. 75 - 82 (2008/10/08)
Neutral trans-bis(diaminocarbene)platinum(II) complexes (2 and 4) and the neutral bis[ { (alkoxy) (amino) }carbene] platinum(II) complex (6) have been successfully synthesized by the reaction of the trans-diiodo[bis(isocyanide) ]platinum(II) complex (1) with amines and alcohols, respectively. The reaction of complex 1 with a primary amine in dichloromethane proceeds via initial formation of 4, and finally gives a neutral ortho-metallated bis(diaminocarbene)platinum(II) complex (3).
