199382-85-9

Upstream product

• 123-54-6 acetylacetone 
• 106281-44-1 (6-oxocyclohex-1-en-1-yl)methyl acetate 
• 105956-40-9 2-(hydroxymethyl)cyclohex-2-en-1-one 

Downstream Products

• 40420-05-1 1-(3-hydroxy-5,6,7,8-tetrahydronaphthalen-2-yl)ethanone 

Relevant academic research and scientific papers

Et3B-mediated and palladium-catalyzed direct allylation of β-dicarbonyl compounds with Morita-Baylis-Hillman alcohols

A practical and efficient palladium-catalyzed direct allylation of β-dicarbonyl compounds with both cyclic and acyclic Morita-Baylis-Hillman (MBH) alcohols, using Et3B as a Lewis acid promoter, is described herein. A wide range of the corresponding functionalized allylated derivatives have been obtained in good yields and with high selectivity.

Regiospecific reaction of stabilized carbanions with 2-(acetoxymethyl)-2-cyclohexenone 1: Synthesis of bicyclic dienones

Regiospecific replacement of acetoxy group in 2-(acetoxymethyl)-2-cyclohexenone 1 by stabilizedd carbanions, leads to S(N) 2-type products 2a-g, 5 and 6. Bicyclic dienones 4 are prepared in 'one pot' from the reaction of 2 with K2CO3 in refluxing absolute ethanol.