199463-95-1

Basic information

• Product Name: Ru((C₅H₄N)2)2(OC₆H₄NCHC₆H₄Cl)⁽¹⁺⁾*ClO₄^(1-)=[Ru((C₅H₄N)2)2(OC₆H₄NCHC₆H₄Cl)]ClO₄
• CAS NO: 199463-95-1
• Molecular Weight: 743.568
• Mol File: 199463-95-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ru((C₅H₄N)2)2(OC₆H₄NCHC₆H₄Cl)⁽¹⁺⁾*ClO₄^(1-)=[Ru((C₅H₄N)2)2(OC₆H₄NCHC₆H₄Cl)]ClO₄(CAS DataBase Reference)
• NIST Chemistry Reference: Ru((C₅H₄N)2)2(OC₆H₄NCHC₆H₄Cl)⁽¹⁺⁾*ClO₄^(1-)=[Ru((C₅H₄N)2)2(OC₆H₄NCHC₆H₄Cl)]ClO₄(199463-95-1)
• EPA Substance Registry System: Ru((C₅H₄N)2)2(OC₆H₄NCHC₆H₄Cl)⁽¹⁺⁾*ClO₄^(1-)=[Ru((C₅H₄N)2)2(OC₆H₄NCHC₆H₄Cl)]ClO₄(199463-95-1)

Safety Data

• Hazardous Substances Data: 199463-95-1(Hazardous Substances Data)

Upstream product

• 117909-29-2 N-4-chlorobenzylidene-2-hydroxyaniline 

Relevant articles and documents

Heterochelates of ruthenium(II): Electrochemistry, absorption spectra, and luminescence properties

A series of heterochelates [Ru(bpy)2(L-X)](ClO4) (1-6) derived from the schiff bases of o-aminophenol and p-substituted (X) benzaldehydes, HL-X (X = NO2, Cl, F, Me, OMe and NMe2) have been synthesized and characterized. Cyclic voltammograms of all the complexes, except 6 (X = NMe2), exhibit a reversible RuII/RuIII and an irreversible RuIII/RuIV oxidation processes. In the case of 6, both the oxidation processes take place reversibly. A linear correlation is obtained by plotting the E1/2 value of RuII/RuIII couple against the Hammett σ+ parameters. The absorption spectra of the complexes are similar showing absorption bands due to dπ-π* (bpy), Schiff base n-π* and π-π* intraligand transitions. A linear correlation is also obtained between vmax (MLCT) and ΔE1/2 (separation between the first oxidation and first reduction couples). The effect of solvents on the MLCT and n-π* absorption bands have been studied. Fluorescent spectral studies have shown that all the complexes luminesce at room temperature and the observed emission bands are due to metal-perturbed ligand-centred transitions.