19950-77-7

Basic information

• Product Name: Oxiranemethanol, 3-phenyl-, acetate, (2R,3S)-rel-
• CAS NO: 19950-77-7
• Molecular Formula: C11H12O3
• Molecular Weight: 192.214
• Mol File: 19950-77-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Oxiranemethanol, 3-phenyl-, acetate, (2R,3S)-rel-(CAS DataBase Reference)
• NIST Chemistry Reference: Oxiranemethanol, 3-phenyl-, acetate, (2R,3S)-rel-(19950-77-7)
• EPA Substance Registry System: Oxiranemethanol, 3-phenyl-, acetate, (2R,3S)-rel-(19950-77-7)

Safety Data

• Hazardous Substances Data: 19950-77-7(Hazardous Substances Data)

Upstream product

• 93-59-4 Perbenzoic acid 
• 21040-45-9 Cinnamyl acetate 
• 103-54-8 cinnamyl acetate 

Downstream Products

• 144969-07-3 erythro-3-chloro-2-hydroxy-3-phenylpropyl acetate 

Relevant articles and documents

Manganese(II)/Picolinic Acid Catalyst System for Epoxidation of Olefins

An in situ generated catalyst system based on Mn(CF3SO3)2, picolinic acid, and peracetic acid converts an extensive scope of olefins to their epoxides at 0 °C in 5 min, with remarkable oxidant efficiency and no evidence of radical behavior. Competition experiments indicate an electrophilic active oxidant, proposed to be a high-valent Mn = O species. Ligand exploration suggests a general ligand sphere motif contributes to effective oxidation. The method is underscored by its simplicity and use of inexpensive reagents to quickly access high value-added products.

Epoxidation of olefins at low temperature using m-chloroperbenzoic acid

Epoxidation of olefins using m-chloroperbenzoic acid in dichloromethane without catalyst at low temperature is described.