199525-24-1

Upstream product

• 199525-12-7 (4aS,5R,6R,8S,8aS)-(-)-3,4,4a,5,6,7,8,8a-octahydro-5-(2-t-butyldiphenylsiloxyethyl)-5,6,8a-trimethyl-8-trimethylsilylnaphthalen-1(2H)-one 
• 1730-25-2 allylmagnesium bromide 
• 91547-51-2 (4aS,5S,8aS)-(+)-3,4,4a,7,8,8a-Hexahydro-5,8a-dimethyl-5-(prop-2-enyl)naphthalene-1,6(2H,5H)-dione 1-(Ethylene Acetal) 
• 199525-23-0 (4aS,5S,8S,8aS)-5-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5,8a-dimethyl-6-methylene-8-trimethylsilanyl-octahydro-naphthalen-1-one 
• 199525-21-8 C₂₁H₃₈O₄Si 
• 199525-11-6 (4aS,5S,8S,8aS)-(+)-3,4,4a,5,6,7,8,8a-octahydro-5-(2-hydroxyethyl)-6-methenyl-5,8a-dimethyl-8-trimethylsilylnaphthalen-1(2H)-one 1-(ethylene acetal) 
• 199525-20-7 C₂₁H₃₆O₂Si 
• 199525-10-5 (4aS,5S,8S,8aS)-(+)-3,4,4a,7,8,8a-hexahydro-5,8a-dimethyl-5-(2-propenyl)-8-trimethylsilylnaphthalene-1,6(2H,5H)-dione 1-(ethylene acetal) 
• 199525-22-9 (4aS,5S,8S,8aS)-5-(2-Hydroxy-ethyl)-5,8a-dimethyl-6-methylene-8-trimethylsilanyl-octahydro-naphthalen-1-one 
• 199525-19-4 C₁₇H₂₄O₃ 
• 26742-33-6 (4aS)-1,4aβ-dimethyl-4,4a,7,8-tetrahydronaphthalene-2,5(3H,6H)-dione-5-ethyeneacetal 

Downstream Products

• 199525-25-2 (1S,4aS,5R,6R,8S,8aS)-5-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-1-(3-hydroxy-propyl)-5,6,8a-trimethyl-8-trimethylsilanyl-decahydro-naphthalen-1-ol 
• 199525-14-9 (1S,4aS,5R,6R)-(-)-1,2,3,4,4a,5,6,7-octahydro-5-[2-(t-butyldiphenylsiloxy)ethyl]-1-(3-hydroxypropyl)-1,5,6-trimethylnaphthalene 
• 199525-29-6 tert-Butyl-{2-[(1R,2R,5S,8aS)-5-(3-iodo-propyl)-1,2,5-trimethyl-1,2,3,5,6,7,8,8a-octahydro-naphthalen-1-yl]-ethoxy}-diphenyl-silane 
• 199525-15-0 (1S,4aS,5R,6R)-(-)-1,2,3,4,4a,5,6,7-octahydro-5-[2-(t-butyldiphenylsiloxy)ethyl]-1-(4-methyl-4-pentenyl)-1,5,6-trimethylnaphthalene 
• 199525-13-8 (1S,4aS,5R,6R,8S,8aS)-(-)-decahydro-1-[3-(t-butyldimethylsiloxy)propyl]-5-[2-(t-butyldiphenylsiloxy)ethyl]-1-hydroxy-5,6,8a-trimethyl-8-trimethylsilylnaphthalene 

Relevant academic research and scientific papers

Total synthesis of dysidiolide

The cdc25A protein phosphatase inhibitor dysidiolide (1) has been synthesized enantioselectively, starting from the enantiomerically pure ketal enone 2 and using a cationic rearrangement as the key step to produce the fully substituted bicyclic core of th