19962-21-1

Basic information

• Product Name: 3-Fluorobenzyloxybenzene
• Synonyms: Benzene, 1-fluoro-3-(phenoxymethyl)-
• CAS NO: 19962-21-1
• Molecular Formula: C₁₃H₁₁FO
• Molecular Weight: 202
• Mol File: 19962-21-1.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 285.9±15.0 °C(Predicted)
• Appearance: /
• Density: 1.133±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 3-Fluorobenzyloxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Fluorobenzyloxybenzene(19962-21-1)
• EPA Substance Registry System: 3-Fluorobenzyloxybenzene(19962-21-1)

Safety Data

• Hazardous Substances Data: 19962-21-1(Hazardous Substances Data)

Upstream product

• 1195931-70-4 C₁₄H₁₁F₃O₄S 

Downstream Products

• 366-43-8 3-fluorobenzoic acid phenyl ester 

Relevant articles and documents

A Fluorinated Ligand Enables Room-Temperature and Regioselective Pd-Catalyzed Fluorination of Aryl Triflates and Bromides

A new biaryl monophosphine ligand (AlPhos, L1) allows for the room-temperature Pd-catalyzed fluorination of a variety of activated (hetero)aryl triflates. Furthermore, aryl triflates and bromides that are prone to give mixtures of regioisomeric aryl fluorides with Pd-catalysis can now be converted to the desired aryl fluorides with high regioselectivity. Analysis of the solid-state structures of several Pd(II) complexes, as well as density functional theory (DFT) calculations, shed light on the origin of the enhanced reactivity observed with L1.