19965-20-9

Basic information

• Product Name: Pd(S₂CO)(PCH₃(C₆H₅)2)2
• CAS NO: 19965-20-9
• Molecular Weight: 599.002
• Mol File: 19965-20-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pd(S₂CO)(PCH₃(C₆H₅)2)2(CAS DataBase Reference)
• NIST Chemistry Reference: Pd(S₂CO)(PCH₃(C₆H₅)2)2(19965-20-9)
• EPA Substance Registry System: Pd(S₂CO)(PCH₃(C₆H₅)2)2(19965-20-9)

Safety Data

• Hazardous Substances Data: 19965-20-9(Hazardous Substances Data)

Upstream product

• 24981-80-4 tetrakis(methyldiphenylphosphine)palladium 
• 463-58-1 carbon oxide sulfide 

Relevant articles and documents

Metal Complexes with Carbon Sulfides and Selenides as Ligands, VI. (Dithiocarbonato-S,S')palladium(II) Complexes through Template Synthesis from Pd(PR3)n and COS, and the Crystal Structure of (PMe2Ph)2Pd(S2CO)

The complexes Pd(PMePh2)4, Pd(PMe2Ph)4 and Pd(PiPr3)2 react with COS to give the (dithiocarbonato-S,S')palladium(II) compounds (PR3)2Pd(S2CO) (1 - 3).The trimethylphosphane complex (PMe3)2Pd(S2CO) (4) is obtained by ligand displacement from 1 - 3 and PMe3.Compound 4 is also formed from BPh4 and COS via BPh4 as intermediate.The X-ray structure analysis of 2 shows a nearly square-planar coordination of the metal and also a planar dithiocarbonate ligand.The reactions of (PPh3)2Pt(η2-COS) with PMe3 or PMe2Ph lead to the formation of the (dithiocarbonato-S,S')platinum(II) complexes (PR3)2Pt(S2CO) (5,6).