199658-11-2

Upstream product

• 545-06-2 trichloroacetonitrile 
• 199658-10-1 2,2-Dimethyl-propionic acid (3R,4S)-3-benzyloxy-4-hydroxy-4-((R)-2-vinyl-oxiranyl)-butyl ester 
• 199658-08-7 2,2-Dimethyl-propionic acid (R)-3-benzyloxy-4-hydroxy-butyl ester 
• 1027169-34-1 2,2-Dimethyl-propionic acid (R)-3-benzyloxy-4-oxo-butyl ester 
• 199658-07-6 2,2-Dimethyl-propionic acid (R)-3-hydroxy-4-(4-methoxy-benzyloxy)-butyl ester 
• 199658-09-8 2,2-Dimethyl-propionic acid (3R,4R)-3-benzyloxy-4-hydroxy-5-methylene-hept-6-enyl ester 

Downstream Products

• 199658-16-7 (4R,5S)-4-[(E)-(R)-1-Benzyloxy-10-(2-hexyl-[1,3]dioxolan-2-yl)-dec-3-enyl]-2,2-dimethyl-5-(2,2,2-trichloro-acetylamino)-[1,3]dioxane-5-carboxylic acid methyl ester 
• 199658-14-5 (4R,5S)-4-[(R)-1-Benzyloxy-3-(2,2-dimethyl-propionyloxy)-propyl]-2,2-dimethyl-5-(2,2,2-trichloro-acetylamino)-[1,3]dioxane-5-carboxylic acid methyl ester 
• 199658-13-4 2,2-Dimethyl-propionic acid (3R,4R,5S)-3-benzyloxy-4-hydroxy-5-hydroxymethyl-5-(2,2,2-trichloro-acetylamino)-hept-6-enyl ester 
• 199658-15-6 (4R,5S)-4-((R)-1-Benzyloxy-3-oxo-propyl)-2,2-dimethyl-5-(2,2,2-trichloro-acetylamino)-[1,3]dioxane-5-carboxylic acid methyl ester 
• 199658-12-3 2,2-Dimethyl-propionic acid (R)-3-benzyloxy-3-((4S,5R)-4-hydroxymethyl-2-trichloromethyl-4-vinyl-4,5-dihydro-oxazol-5-yl)-propyl ester 

Relevant academic research and scientific papers

A novel enantioselective synthesis of (+)-myriocin based on the chemistry of 1-trimethylsilylbuta-2,3-dienes

A synthesis of (+)-myriocin has been achieved in a highly stereoselective manner employing TiCl4 catalyzed addition of 1- trimethylsilylbuta-2,3-diene to an aldehyde and Et2AICI catalysed cyclization of an epoxytrichloroacetimidate f