199847-66-0Relevant academic research and scientific papers
Enethiolizable thioacylsilanes as intermediates for the synthesis of thietanols, thiolanols, and thianols
Bonini, Bianca F.,Franchini, Mauro Comes,Fochi, Mariafrancesca,Mangini, Simone,Mazzanti, Germana,Ricci, Alfredo
, p. 2391 - 2399 (2007/10/03)
Thietanols, thiolanols, and thianols (tetrahydro-2H-thiopyran-3-ols) can be obtained by a fluoride-mediated cyclization of (Z)-α-silyl vinyl sulfides containing an ω-carbonyl function in the chain bonded to the sulfur.
Desilylation of (Z)-α-dimethylphenylsilyl vinyl sulfides with fluoride ion: Revised mechanism for phenyl group migration in substrates containing an electron-withdrawing group β to the sulfur
Bonini, Bianca Flavia,Franchini, Mauro Comes,Fochi, Mariafrancesca,Mazzanti, Germana,Ricci, Alfredo
, p. 3211 - 3217 (2007/10/03)
A detailed investigation of the desilylation of (Z)-α-dimethylphenylsilyl vinyl sulfides with fluoride ion has shown that in substrates containing an electron-withdrawing group β to the sulfur, phenyl group migration occurs as a result of a fluoride ion catalyzed retro-Michael reaction.
