19985-30-9Relevant articles and documents
Kinetic study of the reactions of some 5-nitro-2-(4-nitrophenoxy)-3-x-thiophenes with aniline and 4-methoxyaniline in methanol
Frenna, Vincenzo,Macaluso, Gabriella,Consiglio, Giovanni,Guernelli, Susanna,Spinelli, Domenico
, p. 1877 - 1892 (2007/10/03)
The rate constants of the title reactions have been measured at various amine concentrations. The second-order kinetic constant for the amino substitution increases in a hyperbolic way as a function of the nucleophile concentration. The k3Am/k-1 ratio for each catalysed system is not a monotonic function of the X substituent. This result has been rationalized in the framework of the SB-GA (Specific Base-General Acid) mechanism of base catalysis.
Process for the preparation of aromatic amines
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, (2008/06/13)
Electrophilic aromatic compounds can be reacted with sulphenamides in the presence of bases to form the corresponding aromatic amines.