199850-99-2

Upstream product

• 23558-05-6 3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose 
• 152401-16-6 [4-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-ylmethyl)-2,6-dimethoxy-phenoxy]-tert-butyl-dimethyl-silane 
• 75-08-1 ethanethiol 

Downstream Products

• 199851-13-3 5-[(2R,3S,4R,5S)-3-Benzyloxy-2,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-6-nitro-hexyl]-2-(tert-butyl-dimethyl-silanyloxy)-1,3-dimethoxy-benzene 
• 199851-15-5 4-[(2R,3S,4R,5S)-3-Benzyloxy-2,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-6-nitro-hexylidene]-2,6-dimethoxy-cyclohexa-2,5-dienone 
• 199851-14-4 4-[(2R,3S,4R,5S)-3-Benzyloxy-2,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-6-nitro-hexyl]-2,6-dimethoxy-phenol 
• 1054659-68-5 (S)-1-{(2R,4S,5S,6R)-5-Benzyloxy-6-[4-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethoxy-benzyl]-2-phenyl-[1,3]dioxan-4-yl}-2-nitro-ethanol 
• 199851-00-8 (2R,3S,4R)-3-Benzyloxy-2,4-bis-(tert-butyl-dimethyl-silanyloxy)-5-[4-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethoxy-phenyl]-pentanal 
• 199851-10-0 (2R,4R,5S,6R)-5-Benzyloxy-6-[4-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethoxy-benzyl]-2-phenyl-[1,3]dioxane-4-carbaldehyde 

Relevant academic research and scientific papers

An approach to the narciclasine alkaloids via a quinone methide initiated cyclization reaction

The stereoselective synthesis of a possible intermediate for the synthesis of the narciclasine alkaloids from D-glucose is described. The key step of the sequence is a quinone methide initiated cyclization reaction.