199875-98-4Relevant academic research and scientific papers
Two alternative routes for the migratory insertion of a carbene ligand into a C-H bond
Herber, Ulrich,Bleuel, Elke,Gevert, Olaf,Laubender, Matthias,Werner, Helmut
, p. 10 - 12 (1998)
Reaction of [(η5-C5H5)Rh(=CPh2)(PiPr 3)] (2) with either PF3 or HX (X = Cl, CF3CO2) leads to a migratory insertion of the carbene ligand into one of the C-H bonds of the cyclopentadienyl ring. The X-ray crystal structures of [(η5-C5H4CHPh2)Rh(PF 3)(PiPr3)] (5) and [(η5-C5H4CHPh2)RhCl 2(PiPr3)] (7a) have been determined.
PX3-induced migratory insertion reactions of half-sandwich-type carbenerhodium(I) complexes
Herber,Guerrero Sanchez,Gevert,Laubender,Werner
, p. 396 - 399 (2007/10/03)
The carbenerhodium(I) complexes trans-[RhCl(=CPh2)(L)2] (L = PPri3, 1a; SbPri3, 1b) react with PF3 by cleavage of the rhodium-carbene bond to give the corresponding PF3/sub
