199920-91-7

Basic information

• Product Name: 1-(tert-butyldiphenylsiloxy)-3-deuterio-2-propyne
• Synonyms: 1-(tert-butyldiphenylsiloxy)-3-deuterio-2-propyne
• CAS NO: 199920-91-7
• Molecular Weight: 295.461
• Mol File: 199920-91-7.mol

Chemical Properties

• CAS DataBase Reference: 1-(tert-butyldiphenylsiloxy)-3-deuterio-2-propyne(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(tert-butyldiphenylsiloxy)-3-deuterio-2-propyne(199920-91-7)
• EPA Substance Registry System: 1-(tert-butyldiphenylsiloxy)-3-deuterio-2-propyne(199920-91-7)

Safety Data

• Hazardous Substances Data: 199920-91-7(Hazardous Substances Data)

Upstream product

• 88159-06-2 tert-butyl(diphenyl)(2-propynyloxy)silane 

Relevant articles and documents

Transmetalation of Alkylboranes to Palladium in the Suzuki Coupling Reaction Proceeds with Retention of Stereochemistry

Deuterium-labeling experiments demonstrate that the transmetalation step of the Suzuki coupling reaction of alkylboranes and α-iodoenones proceeds with retention of stereochemistry.

A Cooperative Strategy for the Highly Selective Intermolecular Oxycarbonylation Reaction of Alkenes using a Palladium Catalyst

A novel method for intermolecular functionalization of terminal and internal alkenes has been designed. The electrophilic reagent, hypervalent iodine, plays a key role in this process by activating the alkene C=C bond for nucleophilic addition of the palladium catalyst. This process generates an iodonium-containing palladium species which undergoes CO insertion. The new approach, intermolecular oxycarbonylaton reactions of alkenes, has been achieved and carried out under mild reaction conditions to produce the corresponding β-oxycarbonylic acids with excellent efficiencies and levels of regio- and diastereoselectivity.